Research Progress on Catalytic Conversion of Cellulose to Glucose and Polyols
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摘要: 自然界中含量最丰富的纤维素，是一种清洁可再生的碳资源，可以替代石油等不可再生资源催化转化为高附加值的平台化合物。本文简要介绍了纤维素的结构，指出了纤维素水解及高效转化的关键步骤，并全面综述了纤维素转化为葡萄糖、山梨醇和乙二醇的工艺条件（如催化剂种类、反应温度、反应时间等）及催化机理，并展望了各工艺过程中催化剂的研究方向，旨在为纤维素催化转化为小分子平台化合物的生产提供参考。Abstract: As a clean and renewable carbon resource, cellulose is an alternative for non-renewable resources such as oil and can convert into high value adding molecule platform chemicals. This paper briefly overviews the structure of cellulose and points out the critical steps of cellulose hydrolysis and efficient conversion, and reviewes the process conditions and catalytic mechanism comprehensively for the conversion of cellulose into glucose, sorbitol and ethylene glycol (such as catalyst types, reaction temperature, reaction time, etc.). The research direction of catalysts in each process is prospected, which would be the reference for the catalytic conversion of cellulose into small molecule platform compounds in future.
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Key words:
- cellulose /
- catalytic conversion /
- glucose /
- sorbitol /
- ethylene glycol
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图 5 酸性咪唑离子液体催化纤维素的水解示意图
Figure 5. Schematic diagram of hydrolysis of cellulose catalyzed by acidic imidazole ionic liquid
图 6 Br?nsted酸位点的固体酸水解纤维素图
Figure 6. Illustration of cellulose hydrolyzed by solid acid at br?nsted acid site
图 7 Mn-Fe-Al复合金属氧化物催化纤维素的水解示意图
Figure 7. Schematic diagram of hydrolysis of cellulose catalyzed by Mn-Fe-Al composite metal oxide
图 8 一锅法加氢催化纤维素转化为山梨醇和甘露醇
Figure 8. Schematic representation of hydrolytic hydrogenation of cellulose to sorbitol and mannitol by one-pot method
图 9 纤维素一锅法氢解制备乙二醇的工艺路线
Figure 9. Schematic representation of hydrogenolysis of cellulose to ethylene glycol by one-pot method
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